Inorganic Syntheses, Vol. 22 by Smith L. Holt

Inorganic

By Smith L. Holt

The volumes during this carrying on with sequence supply a compilation of present concepts and concepts in inorganic man made chemistry. contains inorganic polymer syntheses and education of significant inorganic solids, syntheses utilized in the advance of pharmacologically energetic inorganic compounds, small-molecule coordination complexes, and similar compounds. additionally includes helpful details on transition organometallic compounds together with species with metal-metal cluster molecules. All syntheses awarded the following were verified.

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Y. Zavalij, L. Isaacs, J. Am. Chem. Soc. X. L. S. B. S. Zheng, Inorg. Chem. Comm. 1085, 11 (2008) Chapter 3 Coordination Polymers of Cucurbit[n]urils with Metal Ions Abstract The recent work has revealed that Q[n]-based coordination chemistry is gradually changing from simple coordination to novel polydimensional coordination polymers of metal ions to Q[n]s. In particular, our recent study revealed that the coordination of Q[n]s with metal ions in the presence of a third species (often an anionic species or an organic molecule), that is, a structure inducer, can result in the formation of various cucurbit[n]uril-based polydimensional supramolecular coordination architectures and polymers.

18c). 16. As discussed already for Q[5]-based complex systems [24], there are also examples of Q[6] systems prepared in the presence of added small organic molecules that appear to play a structure directing role. 19a) [48]. In the above assembly the water molecules coordinated to the Gd3+ center are hydrogen bonded to carbonyl groups of Q[6], with the cavity of the Q[6] molecule encapsulating a pyridine molecule. 19b), while a water molecule occupies the other half. The La3+ center is bound to two adjacent carbonyl oxygens, a bidentate nitrato ligand and six aqua ligands to yield a coordination number of ten.

Zheng, Inorg. Chem. Comm. 1085, 11 (2008) Chapter 3 Coordination Polymers of Cucurbit[n]urils with Metal Ions Abstract The recent work has revealed that Q[n]-based coordination chemistry is gradually changing from simple coordination to novel polydimensional coordination polymers of metal ions to Q[n]s. In particular, our recent study revealed that the coordination of Q[n]s with metal ions in the presence of a third species (often an anionic species or an organic molecule), that is, a structure inducer, can result in the formation of various cucurbit[n]uril-based polydimensional supramolecular coordination architectures and polymers.

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