Combinatorial Materials Development by Ripudaman Malhotra (Eds.)

Chemical Engineering

By Ripudaman Malhotra (Eds.)

content material: Combinatorial chemistry of fabrics, polymers, and catalysts / Wilhelm F. Maier ... [et al.] --
Combinatorial polymer technology : synthesis and characterization / J. Carson Meredith ... [et al.] --
The compositional unfold method of high-dielectric consistent fabrics and fabrics for built-in optics / L.F. Schneemeyer ... [et al.] --
Chemically delicate high-throughput parallel research of resin bead-supported combinatorial libraries / J. Lauterbach, C.M. Snively, G.H. Oskarsdottir --
Parallel strain reactor method / P. Wright ... [et al.] --
Conformational research of peptide libraries / Saul G. Jacchieri --
The function of informatics in combinatorial fabrics discovery / Laurel A. Harmon, Steven G. Schlosser, Alan J. Vayda --
constructing combinatorial aid for high-throughput experimentation utilized to heterogeneous catalysis / D. Demuth ... [et al.].

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This is accomplished by preparing samples not one at a time, but rather as sample libraries' containing hundreds to thousands of variable combinations each. High-throughput measurements of relevant chemical and physical properties, combined with informatic data analysis, allow efficient development of structure-processing-property relationships. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2002. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2002. Figure 1.

ACS Symposium Series; American Chemical Society: Washington, DC, 2002. ch002 T F M A A . Although only monomer concentration was varied in the libraries, the authors conclude that the C M synthetic approach would be useful in analyzing other variables such as solvent, crosslinking agent, and polymerization conditions to produce optimum molecularly imprinted polymer sensors. Dickinson et ah (12) report C M synthesis of a sensor library consisting of solvatochromic dyes dissolved in polymer. Permeation of the polymer by volatile solvents induced changes in the dye's solvation environment that were detectable by the fluorescence signal.

Both the discrete and continuous libraries were characterized by monitoring the fluorescence response (via the fiber optic cables) as a function of exposure to saturated organic vapors. The deposition of the library directly onto the measurement probe (fiber optic) makes this work a good example of a combined C M polymer synthesis and characterization. For the particular dye and monomer used, the fluorescence response was found to be a nonlinear function of the concentration. Newkome et al. (26) report a combinatorial strategy for synthesizing dendrimers with modified structure and surface chemistry.

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