Chlorine. International Thermodynamic Tables of the Fluid by S. Angus

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By S. Angus

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Additional info for Chlorine. International Thermodynamic Tables of the Fluid State

Sample text

Comparison of experimental vapour pressure data with values calculated from the equation of state. 7 K. The high temperature, series II, results of Ambrose et al. 7%. , and the series II results of Ambrose et al.. The deviations of the results of Knietsch, of Johnson and McIntosh, of Trautz and Gerwig, and of Harteck are too large to show on this figure. 2 and summarised in Table C. None of the results were used at any stage in the construction of the equation of state. The comparisons of the results with values calculated from the equation of state are shown in figures 16 and 17.

Critical region. 5r' at intervals sufficiently close to define the surface. Second virial coefficient. (lH/lP ) T measurements from atmospheric pressure to as low as is needed to define the zero pressure limit, at temperatures from T to 2T~ at intervals depending on the magnitude of dB/dT. Other Properties. Measurements of the speed of sound and CP in the liquid region are valuable either as checks on the equation of state or for direct use in constructing the equation. Measurements of Cy in the gas phase and of (0 T/aP ) H in any region have little influence on the behaviour of the equation of state.

2 and summarised in Table C. None of the results were used at any stage in the construction of the equation of state. The comparisons of the results with values calculated from the equation of state are shown in figures 16 and 17. 33% respectively. 98% at 240 K. 3% in the temperature range below 400 K. 58%. 2%. Also shown in figures 16 and 17 are the comparisons between the estimated data values used in constructing the equation of state and values calculated from the equation. The deviations are systematic on both the liquid and vapour curve, but due to the greater uncertainties in the estimated densities compared to the estimated vapour pressures, the excellent agreement between the vapour pressures and the equation of state is considered to be more significant.

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