Advances in Solid Oxide Fuel Cells II: Ceramic Engineering by Andrew Wereszczak, Edgar Lara-Curzio, Narottam P. Bansal

Chemical Engineering

By Andrew Wereszczak, Edgar Lara-Curzio, Narottam P. Bansal

As a result of its many capability advantages, together with excessive electric potency and coffee environmental emissions, sturdy oxide gas telephone (SOFC) know-how is the topic of intensive study and improvement efforts by means of nationwide laboratories, universities, and personal industries. In those court cases, foreign scientists and engineers current contemporary technical growth on materials-related facets of gas cells together with SOFC part fabrics, fabrics processing, and cell/stack layout, functionality, and balance. rising traits in electrochemical fabrics, electrodics, interface engineering, long term chemical interactions, and extra are included.

This ebook is compiled of papers offered on the complaints of the thirtieth foreign convention on complex Ceramics and Composites, January 22-27, 2006, Cocoa seashore, Florida. prepared and backed through the yank Ceramic Society and the yank Ceramic Society's Engineering Ceramics department along side the Nuclear and Environmental expertise Division.Content:
Chapter 1 improvement of 2 sorts of Tubular SOFCS at TOTO (pages 3–12): Akira Kawakami, Satoshi Matsuoka, Naoki Watanbe, Takeshi Saito, Akira Ueno, Tatsumi Ishihara, Natsuko Sakai and Haarumi Yokokawa
Chapter 2 improvement of sturdy Oxide gasoline telephone Stack utilizing Lanthanum Gallate?Based Oxide as an Electrolyte (pages 16–25): T. Yamada, N. Chitose, H. Etou, M. Yamada, ok. Hosoi, N. Komada, T. Inagaki, F. Nishiwaki, okay. Hashino, H. Yoshida, M. Kawano, S. Yamasaki and T. Ishihara
Chapter three Anode Supported LSCM?LSGM?LSM stable Oxide gas telephone (pages 27–34): Alidad Mohammadi, Nigel M. Sammes, Jakub Pusz and Alevtina L. Smirnova
Chapter four impression of Anode Thickness at the Electrochemical functionality of unmarried Chamber reliable Oxide gas Cells (pages 37–45): B. E. Buergler, Y. Santschi, M. Felberbaum and L. J. Gauckler
Chapter five research of functionality Degradation of SOFC utilizing Chromiumcontaining Alloy Interconnects (pages 47–54): D. R. Beeaff, A. Dinesen and P. V. Hendriksen
Chapter 6 Degradation Mechanism of steel Supported Atmospheric Plasma Sprayed good Oxide gas Cells (pages 55–65): D. Hathiramani, R. Va?en, J. Mertens, D. Sebold, V. A. C. Haanappel and D. Stover
Chapter 7 impression of Transition steel Ions at the Conductivity and balance of Stabilised Zirconia (pages 67–78): D. Lybye and M. Mogensen
Chapter eight Thermophysical homes of YSZ and Ni?YSZ as a functionality of Temperature and Porosity (pages 79–85): M. Radovic, E. Lara?Curzio, R. M. Trejo, H. Wang and W. D. Porter
Chapter nine actual homes within the Bi2O3?Fe2O3 process Containing Y2O3 and CaO Dopants (pages 87–93): Hsin?Chai Huang, Yu?Chen Chang and Tzer?Shin Sheu
Chapter 10 electric homes of Ce0.8Gd0.2O1.9 Ceramics ready through an Aqueous technique (pages 95–103): Toshiaki Yamaguchi, Yasufumi Suzuki, Wataru Sakamoto and Shin?Ichi Hirano
Chapter eleven Structural learn and Conductivity of BaZr0.90Ga0.10O2.95 (pages 105–117): Istaq Ahmed, Elisabet Ahlberg, Sten Eriksson, Christopher Knee, Maths Karlsson, Aleksandar Matic and Lars Borjesson
Chapter 12 Hydrogen Flux in Terbium Doped Strontium Cerate Membrane (pages 119–123): Mohamed M. Elbaccouch and Ali T?Raissi
Chapter thirteen A Mechanical?Electrochemical conception of Defects in Ionic Solids (pages 125–136): Narasimhan Swaminathan and Jianmin Qu
Chapter 14 Nanostructured Ceramic Suspensions for Electrodes and the Brazilian SOFC community “REDE PaCOS” (pages 138–152): R. C. Cordeiro, G. S. Trindade, R. N. S. H. Magalhaes, G. C. Silva, P. R. Villalobos, M. C. R. S. Varela and P. E. V. de Miranda
Chapter 15 Modeling of MIEC Cathodes: The influence of Sheet Resistance (pages 153–160): David S. Mebane, Erik Koep and Meilin Liu
Chapter sixteen Cathode Thermal Delamination research for a Planar strong Oxide gasoline cellphone with useful Graded homes: Experimental research and Numerical effects (pages 161–173): Gang Ju, Kenneth Reifsnider and Jeong?Ho Kim
Chapter 17 Electrochemical features of Ni/Gd?Doped Ceria and Ni/Sm?Doped Ceria Anodes for SOFC utilizing Dry Methane gas (pages 175–182): Caroline Levy, Shinichi Hasegawa, Shiko Nakamura, Manabu Ihara and Keiji Yamahara
Chapter 18 regulate of Microstructure of NiO?SDC Composite debris for improvement of excessive functionality SOFC Anodes (pages 183–191): Koichi Kawahara, Seiichi Suda, Seiji Takahashi, Mitsunobu Kawano, Hiroyuki Yoshida and Toru Inagaki
Chapter 19 Electrochemical Charactarization and id of response websites in Oxide Anodes (pages 193–198): T. Nakamura, okay. Yashiro, A. Kaimai, T. Otake, okay. Sato, G. J. Park, T. Kawada and J. Mizusaki
Chapter 20 Corrosion functionality of Ferritic metal for SOFC Interconnect purposes (pages 200–209): M. Ziomek?Moroz, G. R. Holcomb, B. S. Covino, S. J. Bullard, P. D Jablonski and D. E. Alman
Chapter 21 hot temperature Corrosion habit of Oxidation Resistant Alloys less than SOFC Interconnect twin Exposures (pages 211–221): Zhenguo Yang, Greg W. Coffey, Joseph P. Rice, Prabhakar Singh, Jeffry W. Stevenson and Guan?Guang Xia
Chapter 22 Electro?Deposited protecting Coatings for Planar strong Oxide gasoline cellphone Interconnects (pages 223–229): Christopher Johnson, Chad Schaeffer, Heidi Barron and Randall Gemmen
Chapter 23 homes of (Mn,Co)3O4 Spinel security Layers for SOFC Interconnects (pages 231–240): Zhenguo Yang, Xiao?Hong Li, Gary D. Maupin, Prabhakar Singh, Steve P. Simner, Jeffry W. Stevenson, Guan?Guang Xia and Xiaodong Zhou
Chapter 24 gasoline mobilephone Interconnecting Coatings Produced through diversified Thermal Spray strategies (pages 241–251): E. Garcia and T. W. Coyle
Chapter 25 floor amendment of Alloys for more advantageous Oxidation Resistance in SOFC functions (pages 253–262): David E. Alman, Paul D. Jablonski and Steven C. Kung
Chapter 26 Composite Seal improvement and assessment (pages 264–272): Matthew M. Seabaugh, Kathy Sabolsky, Gene B. Arkenberg and Jerry L. Jayjohn
Chapter 27 research of SOFC?Gaskets Containing Compressive Mica Layers lower than twin surroundings stipulations (pages 273–285): F. Wiener, M. Bram, H.?P. Buchkremer and D. Sebold
Chapter 28 functionality of Self?Healing Seals for stable Oxide gas Cells (SOFC) (pages 287–295): Raj N. Singh and Shailendra S. Parihar
Chapter 29 houses of Glass?Ceramic for strong Oxide gas Cells (pages 297–304): S. T. Reis, R. ok. forehead, T. Zhang and P. Jasinski
Chapter 30 Mechanical habit of reliable Oxide gas phone (SOFC) Seal Glass?Boron Nitride Nanotubes Composite (pages 305–314): Sung R. Choi, Narottam P. Bansal, Janet B. Hurst and Anita Garg
Chapter 31 Mechanical Behaviour of Glassy Composite Seals for IT?SOFC program. (pages 315–323): ok. A. Nielsen, M. Solvang, S. B. L. Nielsen and D. Beeaff
Chapter 32 Mechanical estate Characterizations and function Modeling of SOFC Seals (pages 325–335): Brian J. Koeppel, John S. Vetrano, Ba Nghiep Nguyen, Xin sunlight and Moe A. Khaleel
Chapter 33 Fracture try out of skinny Sheet Electrolytes (pages 338–346): Jurgen Malzbender, Rolf W. Steinbrech and Lorenz Singheiser
Chapter 34 Failure Modes of skinny Supported Membranes (pages 347–360): P. V. Hendriksen, J. R. Hogsberg, A. M. Kjeldsen, B. F. Sorensen and H. G. Pedersen
Chapter 35 comparability of Mechanical homes of NiO/YSZ via varied equipment (pages 361–372): Dustin R. Beeaff, S. Ramousse and Peter V. Hendriksen
Chapter 36 Fracture sturdiness and gradual Crack development habit of Ni?YSZ and YSZ as a functionality of Porosity and Temperature (pages 373–381): M. Radovic, E. Lara?Curzio and G. Nelson
Chapter 37 impact of Thermal biking and Thermal getting older at the Mechanical houses of, and Residual Stresses in, Ni?YSZ/YSZ Bi?Layers (pages 383–391): E. Lara?Curzio, M. Radovic, R. M. Trejo, C. Cofer, T. R. Watkins and okay. L. More
Chapter 38 Three?Dimensional Numerical Simulation instruments for Fracture research in Planar stable Oxide gasoline Cells (SOFCs) (pages 393–405): Janine Johnson and Jianmin Qu
Chapter 39 Electrochemistry and On?Cell Reformation Modeling for good Oxide gas phone Stacks (pages 408–418): ok. P. Recknagle, D. T. Jarboe, okay. I. Johnson, V. Korolev, M. A. Khaleel and P. Singh
Chapter forty Modeling of Heat/Mass delivery and Electrochemistry of an outstanding Oxide gasoline mobile (pages 419–433): Yan Ji, J. N. Chung and Kun Yuan

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Additional info for Advances in Solid Oxide Fuel Cells II: Ceramic Engineering and Science Proceedings, Volume 27, Issue 4

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There seemed to be an ideal gas flow to the anode, where regularly shaped voltage-current characteristics could be obtained. This range was 150-250 mumin for the 9 pin thick anode. 150-500 ml/min for the 21 pn thick anode and 150-1000 m l h i n for the 60 pm thick electrodes. The cell with the 60 pm thick anode showed the highest OCV and the highest po-er output. The reason for this drop was the unstable behaviour (Figure 4) of the thin anode, which caused irregular voltage-current characteristics of this cell, as shown already in Figure 6.

Bode plot of cellhterconnect (bottom) and comparable single cell (top) taken during humidification of cathode gas stream. The equivalency i n the loss of cell performance during operation in humidified air means that it is impossible to deduce the intluence of uater content on cell degradation in the presence of the interconnect. However. there are slight variations observed betneen the impedance 52 . Advances in Solid Oxide Fuel Cells II Performance Degradation of SOFC Using Chromium-ContainingAlloy Interconnects spectra.

Suzuki, F. Dogan and H. U. Anderson, "Impedance spectroscopy of single chamber SOFC", SolidSrure lonics. 175, 35 (2004). 44 . Advances in Solid Oxide Fuel Cells I I Influenceof Anode Thickness on Electrochemical Performance ?. C. Stefan, C. P. Jacobson, S. J. Visco and L. C. De Jonghe, "Single Chamber Fuel Cells: Flow Geometry, Rate, and Composition Considerations", Electrochem. Solid St.. 7, A198 (2004). 'T. Suzuki, P. Jasinski, H. U. Anderson and F. Dogan, "Single Chamber Electrolyte Supported SOFC Module", Electrochem.

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